| Low-Density Polyethylene LDPE |
0.910–0.940 |
105–115 |
4 |
1933 |
Eric Fawcett & Reginald Gibson |
ICI, Northwich, England |
Film, bags, squeeze bottles |
| High-Density Polyethylene HDPE |
0.941–0.965 |
120–130 |
2 |
1953 |
Karl Ziegler; commercialized by Phillips Petroleum (Hogan & Banks) |
Germany / USA |
Milk jugs, crates, pipes, drums |
| Polypropylene PP |
0.895–0.920 |
160–166 |
5 |
1954 |
Giulio Natta |
Politecnico di Milano / Montecatini, Italy |
Caps, containers, automotive parts, textiles |
| Polyvinyl Chloride PVC |
1.16–1.45 |
160–210 (processing) |
3 |
1926 (usable form) |
Waldo Semon, B.F. Goodrich (first prepared 1872, Eugen Baumann) |
Akron, USA (Germany) |
Pipes, cables, profiles, flooring |
| Polystyrene PS |
1.04–1.05 |
≈100 (Tg, amorphous) |
6 |
1839 (discovered) / 1930s (commercial) |
Eduard Simon (commercialized by IG Farben) |
Berlin, Germany |
Packaging, disposable cutlery, insulation |
| Polyethylene Terephthalate PET |
1.38–1.41 |
250–260 |
1 |
1941 |
John Rex Whinfield & James Dickson |
Calico Printers’ Assoc., Manchester, England |
Bottles, fibers, food packaging |
| Polycarbonate PC |
1.20–1.22 |
≈150–155 (Tg 147, amorphous) |
7 |
1953 |
Hermann Schnell |
Bayer, Uerdingen, Germany |
Eyewear lenses, CDs, safety equipment |
| Nylon 6,6 (Polyamide) PA |
1.13–1.15 |
255–265 |
7 |
1935 |
Wallace Carothers |
DuPont, Wilmington, USA |
Fibers, gears, bearings, automotive parts |
| Acrylonitrile Butadiene Styrene ABS |
1.04–1.07 |
≈105 (Tg, amorphous) |
7 |
1948 (patented) / 1954 (commercial) |
United States Rubber Co.; commercialized by Borg-Warner |
USA |
Appliance housings, automotive interiors, pipe fittings |
| Polymethyl Methacrylate (Acrylic) PMMA |
1.17–1.20 |
≈100–105 (Tg, amorphous) |
7 |
1933 |
Otto Röhm |
Röhm & Haas, Darmstadt, Germany |
Signage, lenses, sheets, aircraft glazing |
| Polylactic Acid PLA |
1.24–1.25 |
150–160 |
7 |
1932 (synthesized) / 2002 (commercial scale) |
Wallace Carothers (commercialized by Cargill / NatureWorks) |
DuPont, USA (Nebraska, USA) |
Compostable packaging, 3D printing, disposable cutlery |
| Polyurethane PU |
0.02–1.25 (formulation-dependent) |
Thermoset — no single melt point |
7 |
1937 |
Otto Bayer |
Bayer AG, Leverkusen, Germany |
Foams, elastomers, coatings, adhesives |
| Ethylene Vinyl Acetate EVA |
0.92–0.95 |
65–95 |
7 |
1938 / 1960 |
ICI; commercialized by DuPont |
United Kingdom / USA |
Foam footwear soles, hot-melt adhesives |
| Polyoxymethylene (Acetal) POM |
1.41–1.42 |
165–175 |
7 |
1956 |
DuPont |
USA |
Gears, bearings, zippers, precision parts |
| Polytetrafluoroethylene PTFE |
2.14–2.20 |
≈327 (softening) |
7 |
1938 |
Roy Plunkett |
DuPont, New Jersey, USA |
Non-stick coatings, gaskets, seals |
| Thermoplastic Polyurethane TPU |
1.10–1.25 |
150–220 |
7 |
1952 / 1959 |
Charles Schollenberger |
B.F. Goodrich, Ohio, USA |
Phone cases, hoses, industrial wheels |
| EPDM Rubber EPDM |
0.86–0.87 |
Thermoset — no melt point |
7 |
Early 1960s |
DuPont & others |
USA |
Window/door seals, roofing membranes |
| Natural Rubber NR |
0.91–0.92 |
Thermoset — no melt point |
7 |
Vulcanized 1839 |
Charles Goodyear (vulcanization) |
USA |
Tires, footwear, seals |
| Nitrile Rubber NBR |
0.98–1.00 |
Thermoset — no melt point |
7 |
1930/1931 |
Erich Konrad & Eduard Tschunkur |
IG Farben, Germany |
Fuel/oil hoses, gaskets, gloves |
| Silicone Rubber Si |
1.10–1.60 |
Thermoset — no melt point |
7 |
1943 |
Dow Corning Corporation |
USA |
Medical devices, bakeware, seals |
| Polybutylene Adipate Terephthalate PBAT |
1.21–1.27 |
110–120 |
7 |
1998 |
BASF (as Ecoflex®) |
Germany |
Compostable bags, mulch film, flexible packaging |